Sodium borohydride is prepared industrially following the original
method of Schlesinger: sodium hydride is treated with trimethyl borate at
250–270 °C:
B (OCH3)3 + 4 NaH → NaBH4 + 3 NaOCH3
Millions of kilograms are produced annually, far exceeding the
production levels of any other hydride reducing agent. Sodium borohydride can
also be produced by the action of NaH on powdered borosilicate glass.
Sodium borohydride, also known as sodium tetrahydridoborate and
sodium tetrahydroborate, is an inorganic compound with the formula NaBH4. This
white solid, usually encountered as a powder, is a versatile reducing agent
that finds wide application in chemistry, both in the laboratory and on a
technical scale. It has been tested as pretreatment for pulping of wood, but is
too costly to be commercialized. The compound is soluble in alcohols and certain
ethers but reacts with water in the absence of a base.
This is the procedure of its synthesis.
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